@PontiacJim @LATECH @armyadarkness @Lemans guy - thanks to all of you for the help; i think i finally solved my "car won't start when it's warm issue". As usual, i think it was a multitude of problems that needed to be addressed. First and foremost, the car has had a parasitic drain issue since i bought it and i will spend some time figuring that out. In the meantime, i've applied "a hammer to a push pin" approach. Problems encountered:
1) The MSD ignition / distributor cap set up i had was poor quality - the "cheap" distributor cap just melted (i've got pics below) so I'm sure that didn't help
2) The MSD digital ignition 6AL system is extremely sensitive to voltage drops below 12V; with the voltage drain above and running 2 electric fans, electric fuel pump, Vintage Air/Blower, Hi-Torque starter and a pretty good size stereo, i'm using a lot of electricity driving down the road. My voltmeter gauge would drop to below 9V during cranking.
3) Vintage Air ECU kept needing to be reset; apparently MSD digital boxes put out a lot of line noise...and Vintage ECU is also picky about voltage drops....
4) Ordered the wrong MSD HEI distributor....bought the "RACE READY" one without the vacuum can....not a good idea per above!
5) Engine was pinging at low RPMs
6) Need to optimize timing curve
So here is what i did:
1) got the proper MSD distributor with a vacuum can
2) installed a noise filter for MSD digital 6AL power source
3) Installed a 2nd battery in the trunk with Stinger Relay activated by key ignition; this powers the MSD digital ignition and a couple of other things
4) Installed a 250Amp alternator
5) Installed a 2nd voltmeter so i can check voltage to MSD during cranking
Car now starts rights up, been doing so for 3 days whether it's cold, or has been driven around
During startup, voltmeter on cranking battery goes down to 8-9V, 2nd battery voltmeter stays above 12V
Bought some VPRacing/and Turco Racing Fuel concentrate....no more pinging!
Now need to replace valley pan gasket, and tune the timing curve. A bit overkill on the solution but it's working and since it's my daily driver, having a 2nd battery as backup is a good thing IMHO. I will send pictures after i've cleaned up the engine bay and wires in the car. I installed a bunch of switches and relays while i was testing different configurations.
Thank you all for your help and getting me back on the road. Driving my old 2006 Nissan Frontier isn't the same....